
HIGHLIGHTED PUBLICATIONS
“There is excitement, adventure, and challenge, and there can be great art in organic synthesis”
RECENT PUBLICATIONS
Research Articles, Reviews, Patents
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2023
1. Synthesis and Applications of Organic Borazine Materials
Marchionni, D.; Basak, S.; Nazari Khodadadi, A.; Marrocchi, A.; Vaccaro, L.
Adv. Funct. Mater. 2023, accepted.
2. Waste-minimized C(sp3)-H activation for the preparation of fused N-heterocycles
Salameh, N.; Minio, F.; Rossini, G.; Marrocchi, A.; Vaccaro, L.
Green Synth. Catal. 2023, https://doi.org/10.1016/j.gresc.2023.02.004
2022
1. Glycerol valorisation: development of selective protocols for acetals production through tailor-made macroreticular acid resins
Marrocchi, A.; Trombettoni, V.; Campana, F.; Passagrilli, V.; Nazari, A.; Bracciale, M.P.; Santarelli, M.L.; Vaccaro, L.
Catal Today 2022, https://doi.org/10.1016/j.cattod.2022.08.018
2. Effects of Solution-Shearing Process Parameters on Charge Carrier Mobility in Green Solvent-Processed Organic Field-Effect Transistors
Yun, S.; Marrocchi, A.; Vaccaro, L.; Kim, C.
Synth. Metals 2022, 291, 117209
3. Brewer’ Spent Grain (BSG)-based Green Dielectric Materials for Low-Voltage Operating Solution-Processed Organic Field-Effect Transistors
Yun, S.; Kim Y.; Ho, D.; Kim, J.; Kim, H.; Marconi, O.; Marrocchi, A.; Kim, C.
J. Mater. Chem. C 2022, 10, 15194-1519
4. Continuous flow production of ion exchange membranes immobilized on glass support
Vaccaro, L.; Marrocchi, A.; Trombettoni, V.; Narducci, R.; Di Vona, M.L.
PCT Int. Appl. (2022), WO2022144718 A1 2022-07-07
5. Safe and sustainable hydrogen production using liquid organic hydrogen carriers (LOHCS)
Vaccaro, L.; Marrocchi, A.; Valentini, F.
Chimica Oggi/Chemistry Today 2022, 40, 8-11
6. Liquid Organic Hydrogen Carriers (LOHCs) as H-Source for Bio-Derived Fuels and Additives Production
Valentini, F.; Marrocchi, A.; Vaccaro, L.
Adv. Energy Mater. 2022, 12, 2103362 HTML
7. Synthesis, characterization, and thin-film transistor response of benzo[i]pentahelicene-3,6-dione
Bracciale, M.P.; Kwon, G.; Ho, D.; Kim, C.; Santarelli, M.L.; Marrocchi, A.
Molecules 2022, 27, 863 HTML
8. Exploring a New Class of Singlet Fission Fluorene Derivatives by Unveiling the Role of Intramolecular Charge Transfer
Mencaroni, L.; Carlotti, B.; Elisei, F.; Marrocchi, A.; Spalletti, A.
Chem. Sci. 2022,13, 2071-2078 HTML
9. Green solvents processable organic electronic devices in “Sustainable strategies in organic electronics
Campana, F.; Lanari, D.; Marrocchi, A.; Vaccaro, L.
in Marrocchi, A. (ed) Sustainable strategies in organic electronics. Woodhead Publishing Series in Electronic and Optical Materials. Elsevier, 2022
10. Organic electronics: an overview of key materials, processes and devices
Bracciale, M.P.; Kim, C.; Marrocchi, A.
in Marrocchi, A. (ed) Sustainable strategies in organic electronics. Woodhead Publishing Series in Electronic and Optical Materials. Elsevier, 2022
11. Green Solvent-Processed Complementary-like Inverters Based on Ambipolar Organic Thin-film Transistors
Lee, M.; Yun, S.; Ho, D.; Earmme, T.; Marrocchi, A.; Vaccaro, L.; Kim, C.
J. Ind. Eng. Chem. 2022, 105, 231-237 HTML
2021
1. Improving Charge Transport Performance of Solution-Processed Organic Field-Effect Transistors Using Green Solvent Additives
Lee, Y.; Ho, D.; Valentini, F.; Marrocchi, A.; Vaccaro, L.; Kim, C.
J Mater Chem C 2021, 9, 16506-16515 HTML
2. LOHCs (Liquid Organic Hydrogen Carriers) come fonte sicura di idrogeno per processi di valorizzazione della biomassa
Vaccaro, L.; Marrocchi, A.
Chimica e l’Industria 2021, 4, 12-19
3. The carbon-carbon triple bond as a tool to design organic semiconductors for photovoltaic applications: an assessment of prospects and challenges
Seri, M.; Marrocchi, A.
J Mater Chem C, Theme Collection “Special issue in honour of Kees Hummelen, Theme collection “JMCC Hot Paper 2021” and Theme collection "2021 Journal of Materials Chemistry C most popular articles", 2021, 9, 16164-16186 HTML
4. Catalytic Biomass Upgrading Exploiting Liquid Organic Hydrogen Carriers (LOHCs)
Ferlin, F.; Valentini, F.; Marrocchi, A.; Vaccaro, L.
ACS Sustainable Chem. Eng. 2021, 9, 9604–9624 HTLM
5. Valorisation of urban waste to access low-cost heterogeneous palladium catalyst for cross-coupling reactions in biomass-derived γ-valerolactone
Valentini, F.; Ferlin, F.; Lilli, S.; Marrocchi, A.; Liu, P.; Gu, Y.; Vaccaro, L.
Green Chem. 2021, 23, 5887-5895 HTML
6. Principal Component Analysis (PCA) Combined with Naturally Occurring Crystallization Inhibitors: An Integrated Strategy for a more Sustainable Control of Salt Decay in Built Heritage
Cardinali, F.; Bracciale, P.; Santarelli, M.L.; Marrocchi, A.
Heritage 2021, 4, 220–229
7. Process for the treatment of the brewing industry by-products.
Marconi, O.; Marrocchi, A.
Patent Pending, Filed in Italy (2021), No. 102021000021299
2020
1. Molecular Crystallization Inhibitors for Salt Damage Control in Porous Materials: An Overview
Bracciale, P.; Sammut, S.; Cassar, J.; Santarelli, M.L.; Marrocchi, A.
Molecules 2020, 25, 1873 HTML
2. Editorial for “Materials Chemistry” Section on Molecules
Marrocchi, A.
Molecules 2020, 25, 5833 HTML
3. Green solvent-processed organic electronic devices
Campana, F.; Kim, C.; Marrocchi, A.; Vaccaro, A.
J. Mater. Chem. C, 2020, 8, 15027 HTML
4. Green solvents for organic thin-film transistor processing
Ho, D.; Lee, J.; Park, S.; Park, Y; Cho, K.; Campana, F.; Lanari, D.; Facchetti, A.; Seo, S.Y.; Kim, C.; Marrocchi, A.; Vaccaro, L.
J. Mater. Chem. C 2020, 8, 5786-5794 HTML
5. Photoresponsive N,N’-disubstituted indigo derivatives
Sarmento, D.; Cunha, C.; Porciello, A.; Valentini, F.; Marrocchi, A.; Vaccaro, L.; Galvão A.M.; Seixas de Melo, J.S.
Dyes Pigm. 2020, 176, 108197 HTML
2019
1. Experimental analysis of an innovative organic membrane for air to air enthalpy exchangers
Baldinelli, G.; Rotili, A.; Narducci, R.; Di Vona, M.L.; Marrocchi, A.
Int. Commun. Heat Mass Transfer 2019, 108, 104332
2. Scambiatori di calore entalpici a membrane di tipo polimerico aromatico solfonato e procedimento per la preparazione di dette membrane
Di Vona, M. L.; Baldinelli, G.; Marrocchi, A.; Narducci, R.
Patent No. 102016000112268, Granted in Italy
3. The sustainable batch or continuous-flow preparation of biomass derived fuels using sulfonated organic polymers
Trombettoni, V.; Campana, F.; Marrocchi, A.; Vaccaro, L.
in: Green Synthetic Processes and Procedures, Ballini, R. (Ed), Green Chemistry Series N. 61, Royal Society of Chemistry 2019, ISBN: 978-1-78801-512-7
4. Ground-State Structural Disorder and Excited-State Symmetry Breaking in a Quadrupolar Molecule
Soderberg, M.; Dereka, B.; Marrocchi, A.; Carlotti, B.; Vauthey, E.
J. Phys. Chem. Lett. 2019, 10, 2944-2948
5. Formic acid, a bio-derived source of energy and hydrogen for biomass upgrading
Valentini, F.; Kozell, V.; Petrucci, C.; Marrocchi, A.; Gu, Y.; Gelman, D.; Vaccaro, L.
Energy Env. Sci. 2019,12, 2646-2664
6. Polymer-supported bis-1,2,4-triazolium ionic tag framework for an efficient Pd(0) catalytic system in biomass-derived GVL
Valentini, F.; Mahmoudi, H.; Bivona, L.A.; Piermatti, O.; Bagherzadeh, M.; Aprile, C.; Marrocchi, A.; Vaccaro, L.
ACS Sustainable Chem. Eng. 2019, 7, 6939−6946
7. A tailored polymeric cationic tag-anionic Pd(II) complex as catalyst for the low-leaching Heck-Mizoroki coupling in flow and in biomass-derived GVL
Mahmoudi, H.; Valentini, F.; Ferlin, F.; Bivona, L.A.; Anastasiou, I.; Aprile, C.; Marrocchi, A.; Vaccaro, L.
Green Chem., 2019, 21, 355-360
8. Key trends in sustainable approaches to the synthesis of semiconducting polymers
Marrocchi, A.; Trombettoni, V. Sciosci, D.; Campana, F.; Vaccaro, L.
in: Handbook of Organic Materials for Electronic and Photonic Devices, Ostroverkhova, O. (Ed), 2nd Edition, Woodhead Publishing, 2019; ISBN: 9780081022849
2018
1.Boosting biomass valorisation. Synergistic design of continuous flow reactors and water-tolerant polystyrene acid catalysts for a non-stopping production of esters
Trombettoni, V., Sciosci, D.; Bracciale, M.P.; Campana, F.; Santarelli, M.L.; Marrocchi, A.; Vaccaro, L.
Green Chem. 2018, 20, 3149-3396
2. Towards Sustainable C‐H Functionalization Reactions: The Emerging Role of Bio‐Based Reaction Media
Santoro, S.; Marrocchi, A.; Lanari, D.; Ackermann, L.; Vaccaro, L.
Chem. Eur. J. 2018, 24, 13383-13390
3. A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as biomass-derived medium
Ferlin, F.; Luciani, L.; Santoro, S.; Marrocchi, A.; Lanari, D.; Bechtoldt, A.; Ackermann, L.; Vaccaro, L.
Green Chem., 2018, 20, 2888-2893
4. Stabilized SPEEK membranes with high degree of sulfonation for enthalpy heat exchangers
Narducci, R.; Di Vona, M.L.; Marrocchi, A.; Baldinelli, G.
Coatings 2018, 8, 190
5. Green reaction media for cross-coupling reactions. A recent overview and possible directions
Santoro, S.; Ballerini, E.; Marrocchi, A.; Piermatti, O.; Vaccaro, L.
in: Advanced Green Chem. 2018 World Scientific Publishing, pp. 177-204; ISBN: 978-981-3228-10-8 (hardcover); ISBN: 978-981-3228-12-2 (ebook)
6. Recent advances in sulfonated resin catalyst for efficient biodiesel and bioderived additives production
Trombettoni, V.; Lanari, D.; Curini, M.; Prinsen, P.; Luque, R.; Marrocchi, A.; Vaccaro, L.
Prog. Energy Comb. Sci. 2018, 65, 136-162
7. Definition of green synthetic tools based on safer reaction media, heterogeneous catalysis, and flow technology
Vaccaro, L.; Curini, M.; Ferlin, F.; Lanari, D.; Marrocchi, A.; Piermatti, O., Trombettoni, V.
Pure Appl. Chem. 2018, 90, 21-33